The LaTeX command for simeq (≃) is \simeq.
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Write \simeq inside math mode, that is between $…$ for inline math or in a \[ … \] or equation block for display math. It is part of core LaTeX math, so no extra package is required.
As a relation, \simeq gets a thick space on each side, and a long inline formula may break after it. With unicode-math under XeLaTeX or LuaLaTeX, typing ≃ in a formula gives the same symbol. Not to be confused with \approx (≈).
$a \simeq b$Open this example in the live preview: it renders as you type, with no compiler and no signup.
\approx (≈): approximately equal\sim (∼): similar to\cong (≅): congruent / isomorphicRelation symbols in LaTeX: the full table or search all 350+ LaTeX symbols.
Use \simeq in math mode; it needs no extra package. For example, $a \simeq b$.
None: \simeq is built into LaTeX, so no extra package is required.