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The LaTeX command for approx (≈) is \approx — approximately equal.
\approxWrite \approx inside math mode — that is, between $…$ for inline math or in a \[ … \] / equation block for display math. It is part of core LaTeX math, so no extra package is required.
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Use \approx in math mode — it needs no extra package. For example, $a \approx b$.
None — \approx is built into LaTeX's math mode, so no extra package is required.